The Vampire Diaries, Season 1, Episode 12, Unpleasantville
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There’s a new vampire in town, and Stefan and Damon are on the hunt. To protect Elena, Jenna, Jeremy, and Bonnie, Stefan gives Elena jewelry filled with Vervain, so that they can’t be affected by vampires. Damon and Stefan take Elena to a 1950s themed school dance, where Alaric and Damon finally are introduced.
Vampire Diaries, S1E12, Unpleasantville